Synthesis of HS/NH2-Bi-Functional Mesoporous Silica and its Adsorption of Co(II) and Mn(II) in Dilute Solutions

Autor: Yao, Qing Xu, Jia, Ming Chun, Men, Jin Feng
Zdroj: Applied Mechanics and Materials; May 2012, Vol. 178 Issue: 1 p586-590, 5p
Abstrakt: Bi-functional mesoporsous silica adsorbents, functionalized via the introduction of chelating agents (mercaptopropyl and aminopropyl groups) were prepared to adsorb Co2+ and Mn2+ in dilute solutions. The molar ratio of MPTMS/APTMS in grafting process seemed to have great effected on the mesostructure of adsorbents, and the appropriate value was considered to be 2/1. The modified silica gels at that ratio showed well-ordered property as well as its high infinity of the two metal ions. The pseudo-second-order equation was applied to describe the adsorption kinetics. And the influence of interferential ions Ca2+ and Mg2+ was also studied.
Databáze: Supplemental Index