Resolutions of tertiary phosphines and arsines with orthometallated palladium (II)—amine complexes
| Autor: | Wild, S.Bruce |
|---|---|
| Zdroj: | Coordination Chemistry Reviews; November 1997, Vol. 166 Issue: 6 p291-311, 21p |
| Abstrakt: | The use of the homochiral forms of chloro-bridged palladium (II) complexes containing orthometallated N,N-dimethyl(α-methylbenzyl)amines and related naphthylamines for the resolution of trivalent phosphines and arsines chiral at phosphorus and arsenic is reviewed. Work with a wide variety of ligands is discussed and references to applications of the ligands as probes of inorganic stereochemistry and as auxiliaries for asymmetric synthesis are given. Most examples have been taken from work carried out in the author's laboratories. © 1997 Elsevier Science S.A. |
| Databáze: | Supplemental Index |
| Externí odkaz: |
|
Full Text from ScienceDirect