Pseudophomins A and B, a class of cyclic lipodepsipeptides isolated from a Pseudomonasspecies

Autor: Quail, J. Wilson, Ismail, Nargis, Pedras, M. Soledade C., Boyetchko, Susan M.
Zdroj: Acta Crystallographica Section C: Crystal Structure Communications; May 2002, Vol. 58 Issue: 5 po268-o271, 4p
Abstrakt: The crystal structures of pseudophomins A and B, with primary structures β‐hydroxy­decanoyl–l‐Leu–d‐Glu–d‐allo‐Thr–d‐Ile–d‐Leu–d‐Ser–l‐Leu–d‐Ser–l‐Ile monohydrate, C55H97N9O16·H2O, and β‐hydroxy­dodecanoyl–l‐Leu–d‐Glu–d‐allo‐Thr–d‐Ile–d‐Leu–d‐Ser–l‐Leu–d‐Ser–l‐Ile monohydrate, C57H101N9O16·H2O, new cyclic lipodepsipeptides isolated from Pseudomonas fluorescensstrain BRG100, have been solved. The absolute configuration of pseudophomin A has been determined from anomalous dispersion and the stereochemistry of the β‐hydroxy acid group is R.
Databáze: Supplemental Index