| Autor: |
Gallagher, John F., Hudson, Richard D. A., Manning, A. R. |
| Zdroj: |
Acta Crystallographica Section C: Crystal Structure Communications; January 2001, Vol. 57 Issue: 1 p28-30, 3p |
| Abstrakt: |
The title compound, [Fe(C5H5)(C10H7O2S)], an important precursor en routeto organometallic donor–π–acceptor systems, forms dimers in the solid state through cyclic intermolecular carboxylic acid O—H⃛O hydrogen bonds, graph set R(8) [O⃛O 2.661 (2) Å and O—H⃛O 175°]. Intermolecular CCp—H⃛πCpinteractions between the unsubstituted cyclopentadienyl (Cp) rings and Cthiazole—H⃛πCpinteractions link neighbouring molecules into a three‐dimensional network [C⃛Cg3.753 (7) Å and C—H⃛Cg156°, and C⃛Cg3.687 (3) Å and C—H⃛Cg129°; Cgis the ring centroid]. Intramolecular C—H⃛O interactions are present, graph set S(7) [C⃛O 2.925 (3) Å and C—H⃛O 120°, and the closest C—H⃛Sthienylcontact has a C⃛S distance of 3.058 (2) Å]. |
| Databáze: |
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