Tetrabromo(2‐methylpyridine‐N)titanate(IV)

Autor: Hensen, Karl, Lemke, Alexander, Bolte, Michael
Zdroj: Acta Crystallographica Section C: Crystal Structure Communications; December 2000, Vol. 56 Issue: 12 pe565-e566, 2p
Abstrakt: The reaction of 2‐methyl­pyridine with TiBr4affords tetra­bromo(2‐methyl­pyridine‐N)­titanate(IV), C6H7Br4NTi. The environment around the Ti atom can be described as a slightly distorted trigonal bipyramid, with the nitro­gen base occupying an equatorial position. The crystal structure of the title compound is isomorphous with tetra­chloro(2‐methyl­pyridine‐N)­titanate(IV).
Databáze: Supplemental Index