Synthesis of Diastereoisomeric 1,2,3-Triphenylindans

Autor: Alesso, Elba N., Finkielsztein, Liliana M., Lantaño, Beatriz, Bianchi, Daniel E., Iglesias, Graciela Y. Moltrasio, Aguirre, Jose M.
Zdroj: Australian Journal of Chemistry; 1997, Vol. 50 Issue: 2 p149-152, 4p
Abstrakt: The stereoisomers of 1,2,3-triphenylindans were synthesized via 1,2,3-triphenylindan-1-ols. The configurational assignments of all the compounds were made by chemical and spectroscopic methods. An unexpected compound was isolated as a by-product of the Grignard reactions and was identified as r-2-hydroxy-2, t-3-diphenylindan-1-one.
Databáze: Supplemental Index