| Autor: |
Balboni, Davide, Moscardi, Gilberto, Baruzzi, Giovanni, Braga, Vittorio, Camurati, Isabella, Piemontesi, Fabrizio, Resconi, Luigi, Nifant'ev, Ilya E., Venditto, Vincenzo, Antinucci, Simona |
| Zdroj: |
Macromolecular Chemistry and Physics; June 2001, Vol. 202 Issue: 10 p2010-2028, 19p |
| Abstrakt: |
Details of the preparation and polymerization behavior of two chiral zirconocene catalysts are presented. The results of experimental and molecular-mechanics evaluation of their stereoselectivity with respect to liquid-propene polymerization are compared with those of a related catalyst system. The elastic properties of the obtained amorphous poly(propylene), due to the presence of small γ-form crystallites, are compared with those of a high-molecular weight atactic poly(propylene) obtained in the presence of a C2v catalyst. |
| Databáze: |
Supplemental Index |
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