| Autor: |
Shi, Yili, Blum, Suzanne A. |
| Zdroj: |
Organometallics; 20240101, Issue: Preprints |
| Abstrakt: |
A transmetalation reaction between rhodium(III) and sp2- and sp3-hybridized organogold(I) compounds proceeds rapidly at ambient temperature (15 min to 6 h). Mechanistic experiments demonstrate that ligand dissociation on rhodium(III) precedes transmetalation; synthetic applications of the gold/rhodium transmetalation are highlighted by linking rhodium-mediated C−H activation, conjugate addition, and reductive elimination to transmetalation from organogold compounds. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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