Intensity redistribution of bending and stretching Raman scattering bands in water upon degassing and crystallisation

Autor: Pershin, Sergei M, Bunkin, Aleksei F, Zakharov, S D, Luk, V A
Zdroj: Quantum Electronics; December 2010, Vol. 40 Issue: 12 p1106-1108, 3p
Abstrakt: It is established for the first time that the intensities of deformation and valence Raman scattering (RS) bands in water vary oppositely in the processes of degassing and crystallising. Water degassing shifts the centre of a valence OH band to higher frequencies by approximately 2 cm-1, which points to a reduced contribution of structural complexes to the RS spectrum.
Databáze: Supplemental Index