A Novel Alkene(alkyl)(aqua)(aryl)platinum(II) Complex – [Pt{CH(CH2C6F5)CH2CH2CH=CH2}(C6F5)(OH2)]

Autor: Deacon, Glen B., Drago, Penny R., Göbbels, Dirk, Wickleder, Mathias S., Meyer, Gerd
Zdroj: Zeitschrift für anorganische und allgemeine Chemie; May 2001, Vol. 627 Issue: 5 p811-813, 3p
Abstrakt: From the reaction of PtCl2(hex) (hex = hexa‐1,5‐diene) with LiC6F5in diethyl ether, the complex [Pt{CH(CH2C6F5)CH2CH2CH=CH2}(C6F5)(OH2)] (1) was isolated. The crystal structure (monoclinic, C2/c(no. 15), Z= 8, a= 15.241(3), b= 16.579(2), c= 16.225(2) Å, β = 111.12(2)°) shows a complex with square planar coordination around platinum with a template formed 1‐pentafluorophenylhex‐5‐en‐2‐yl ligand, and C6F5and aqua ligands transto the double bond and alkyl carbon, respectively.
Databáze: Supplemental Index
Externí odkaz: