Autor: |
Dialer, Harald, Schumann, Susanne, Polborn, Kurt, Steglich, Wolfgang, Beck, Wolfgang |
Zdroj: |
European Journal of Inorganic Chemistry; July 2001, Vol. 2001 Issue: 7 p1675-1679, 5p |
Abstrakt: |
Hippuric acid dimers bridged by a C=C double bond react with the chloro-bridged complexes (Cp*)(Cl)M(µ-Cl)2M(Cp*)(Cl) with decarboxylation or loss of a benzoyl group to give the unexpected ligand-bridged dinuclear complexes 2 and 4, which were characterized by X-ray diffraction. In the iridium complex 2 an oxazolone derivative forms a C,O-N,N'-coordinated bridge, whereas in the rhodium complex 4 a chlorine atom and an amide group bridge the two metal atoms. |
Databáze: |
Supplemental Index |
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