Reversible Formation of a Cationic Palladium(II) Hydride [HPd(PPh3)2]+ in the Oxidative Addition of Acetic or Formic Acid to Palladium(0) in DMF

Autor: Amatore, Christian, Jutand, Anny, Meyer, Gilbert, Carelli, Italo, Chiarotto, Isabella
Zdroj: European Journal of Inorganic Chemistry; August 2000, Vol. 2000 Issue: 8 p1855-1859, 5p
Abstrakt: The oxidative addition of acetic or formic acid to Pd0(PPh3)4 in DMF affords a cationic palladium(II) hydride, [trans-HPd(PPh3)2(DMF)]+, with acetate or formate as the counter anion. The two reactions are reversible. The equilibrium and kinetic constants of the oxidative additions have been determined.
Databáze: Supplemental Index