Autor: |
Amatore, Christian, Jutand, Anny, Meyer, Gilbert, Carelli, Italo, Chiarotto, Isabella |
Zdroj: |
European Journal of Inorganic Chemistry; August 2000, Vol. 2000 Issue: 8 p1855-1859, 5p |
Abstrakt: |
The oxidative addition of acetic or formic acid to Pd0(PPh3)4 in DMF affords a cationic palladium(II) hydride, [trans-HPd(PPh3)2(DMF)]+, with acetate or formate as the counter anion. The two reactions are reversible. The equilibrium and kinetic constants of the oxidative additions have been determined. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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