2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene as an η6-Ligand in Transition Metal Complexes

Autor: Binger, Paul, Stutzmann, Stefanie, Stannek, Jörg, Gabor, Barbara, Mynott, Richard
Zdroj: European Journal of Inorganic Chemistry; January 1999, Vol. 1999 Issue: 1 p83-86, 4p
Abstrakt: The η6-1,3,5-triphosphabenzene transition metal complexes 12a,b, 14, and 16 have been synthesized for the first time by the displacement of η6-arene ligands (toluene, benzene and naphthalene) with 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene (9). The new complexes have been fully characterized by a combination of elemental analysis, mass spectrometry, and 1H-, 13C- and 31 P-NMR spectroscopy.
Databáze: Supplemental Index
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