| Autor: |
Belokon, Yuri N., Green, Brendan, Ikonnikov, Nicolai S., Larichev, Vladimir S., Lokshin, Boris V., Moscalenko, Margarita A., North, Michael, Orizu, Charles, Peregudov, Alexander S., Timofeeva, Galina I. |
| Zdroj: |
European Journal of Organic Chemistry; July 2000, Vol. 2000 Issue: 14 p2655-2661, 7p |
| Abstrakt: |
Titanium complexes 1 derived from chiral salen ligands are highly active precatalysts for the asymmetric addition of trimethylsilyl cyanide to aldehydes and ketones. Based on spectroscopic studies and the identification of adducts between complexes 1 and carbonyl compounds or trimethylsilyl cyanide, a catalytic cycle which explains the origin of the asymmetric induction is proposed. Kinetics studies have been carried out, the results of which are consistent with the proposed catalytic cycle. |
| Databáze: |
Supplemental Index |
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