| Autor: |
Wit, Jan B. M., Eijkel, Gerno T. van, Kanter, Franciscus J. J. de, Schakel, Marius, Ehlers, Andreas W., Lutz, Martin, Spek, Anthony L., Lammertsma, Koop |
| Zdroj: |
Angewandte Chemie. International Edition; September 3, 1999, Vol. 38 Issue: 17 p2596-2599, 4p |
| Abstrakt: |
Highly strained methylenephosphiranes are formed in the reaction of the new electrophilic phosphinidene complex [iPr2N−P=Fe(CO)4] with allenes. Remarkably, reaction with diallenes at 0°C also leads to a phosphirane, which rearranges upon warming to room temperature to a bis-isopropylidenephospholene (see scheme). |
| Databáze: |
Supplemental Index |
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