Chemistry of C84: Separation of Three Constitutional Isomers and Optical Resolution of D2-C84 by Using the “Bingel–Retro-Bingel” Strategy

Autor:	Crassous, Jeanne, Rivera, José, Fender, Nicolette S., Shu, Lianhe, Echegoyen, Luis, Thilgen, Carlo, Herrmann, Andreas, Diederich, François
Zdroj:	Angewandte Chemie. International Edition; June 1, 1999, Vol. 38 Issue: 11 p1613-1617, 5p
Abstrakt:	The pure enantiomers of D2-C84 as well as a third constitutional isomer of this higher fullerene were produced by a retro-Bingel reaction on the first organic derivatives of C84 (see scheme). These derivatives were synthesized by Bingel cyclopropenation of C84, separated, and unambiguously structurally characterized.
Databáze:	Supplemental Index
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