| Autor: |
Attinà, Marina, Bernardi, Fernando, Cacace, Fulvio, Rossi, Ivan |
| Zdroj: |
Chemistry - A European Journal; April 1999, Vol. 5 Issue: 4 p1186-1191, 6p |
| Abstrakt: |
A mechanistic linkhas been found between the gas‐phase preparation of ethylenexenonium ions and the reactions of unsaturated compounds with XeF+salts, utilized in solution as stereoselective fluorinating agents. Complex C2H4XeF+(2) is the charged intermediate in the formation process of C2H4Xe+(1) from XeF+and ethylene. This was evidenced through FT‐ICR and TQ mass spectrometry, complemented by DFT calculations at the BLYP/DZVP//CCSD(T) level of theory. |
| Databáze: |
Supplemental Index |
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