Silver-Promoted Reactions of Bicyclo[3.2.1]octadiene Derivatives

Autor: Orugunty, R. S., Wright, D. L., Battiste, M. A., Abboud, K. A.
Zdroj: Organic Letters; June 2002, Vol. 4 Issue: 12 p1997-2000, 4p
Abstrakt: Highly substituted bicyclo[3.2.1]octadiene building blocks are easily prepared from tetrachloro- or tetrabromocyclopropene through reaction with cyclic dienes. These polyhalogenated derivatives can serve as precursors to a variety of functionalized bridged bicyclic compounds. Herein, we report on the generation and reaction of electrophilic species with silver ion.
Databáze: Supplemental Index