Autor: |
Sulikowski, G. A., Agnelli, F., Spencer, P., Koomen, J. M., Russell, D. H. |
Zdroj: |
Organic Letters; May 2002, Vol. 4 Issue: 9 p1447-1450, 4p |
Abstrakt: |
Feeding experiments using a deuterium labeled C16 maleic anhydride and whole cell culture of ATCC 74256 led to the isolation of phomoidride B with deuterium incorporation at C(7) and C(19) as determined by 2H NMR and electrospray mass spectrometry. This result is in accord with a decarboxylative homodimerization of the C16 maleic anhydride as a key biosynthetic step leading to phomoidride B. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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