| Autor: |
Lee, Woo Ram, Ryu, Dae Won, Lee, Jin Wuk, Yoon, Jung Hee, Koh, Eui Kwan, Hong, Chang Seop |
| Zdroj: |
Inorganic Chemistry; 20240101, Issue: Preprints |
| Abstrakt: |
Isostructural lanthanide-organic frameworks were prepared by a solvothermal reaction of the corresponding metal ions and the phosphine-oxide-based tricarboxylate ligand. The gravimetric gas uptake was unexpectedly increased when going from Nd3+to Gd3+, which is associated with the enhanced surface areas and electrostatic interactions between exposed metal ions and gas molecules with quadrupole moments. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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