| Autor: |
Topin, Sylvain, Aupiais, Jean, Baglan, Nicolas |
| Zdroj: |
Radiochimica Acta; February 2010, Vol. 98 Issue: 2 p71-75, 5p |
| Abstrakt: |
AbstractThe interactions of pentavalent Np and Pu with nitrate ligands has been investigated in perchlorate/nitrate media by capillary electrophoresis-inductively coupled plasma mass spectrometry (CE-ICP-MS). The binding constant for the complex PuO2NO3, log10βPuO2NO3°=0.14±0.14, is established for the first time while a new value for NpO2NO3, log10βNpO2NO3°=0.13± 0.14, is proposed. The usual analogy applied between Np(V) and Pu(V) interactions seems to be valid for nitrates. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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