| Autor: |
Rigby, J. H., Bazin, B., Meyer, J. H., Mohammadi, F. |
| Zdroj: |
Organic Letters; March 2002, Vol. 4 Issue: 5 p799-801, 3p |
| Abstrakt: |
The efficient construction of an ingenol intermediate exhibiting inside−outside intrabridgehead stereochemistry is reported. The sequence features the net conversion of a cis-intrabridgehead compound into a highly strained trans-species via palladium-mediated isomerization of an allylic epoxide followed by a low-temperature alkoxide-accelerated 1,5-hydrogen migration. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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