The first supraicosahedral p-block metallacarboranes

Autor: Wilson, Neil M. M., Ellis, David, Boyd, Alan S. F., Giles, Barry T., Macgregor, Stuart A., Rosair, Georgina M., Welch, Alan J.
Zdroj: Chemical Communications; February 28, 2002, Vol. 2002 Issue: 5 p464-465, 2p
Abstrakt: Reaction of Na2[7,9-C2B10H12] or its C-dimethyl analogue with SnCl2 in THF affords 4,1,6-closo-SnC2B10H12 or 1,6-Me2-4,1,6-closo-SnC2B10H10 respectively, the first 13-vertex metallacarboranes involving p-block metals; spectroscopic, structural and theoretical studies, including an analysis of fluctionality in solution, are reported.
Databáze: Supplemental Index