THE ACETYL GROUP MIGRATIONS IN D-GLUCOSEDIETHYL THIOACETYL TETRAÁCETATE

Autor: Lemieux, R.U., Bauer, H. F.
Zdroj: Canadian Journal of Chemistry; April 1954, Vol. 32 Issue: 4 p362-365, 4p
Abstrakt: The D-glucose diethyl thioacetal tetraacetate prepared by Wolfrom and associates both by detritylation of 6-O-trityl-D-glucose diethyl thioacetal tetraacetate and mercaptalation of 2,3,4,6-tetra-O-acetyl-β-D-glucose was obtained by direct acetylation of D-glucose diethyl thioacetal with acetic anhydride and sodium acetate. Methylation of the tetraacetate followed by deacetylation and demercaptalation gave only 2-O-methyl glucose and methyl β-D-glucopyranoside.
Databáze: Supplemental Index