| Autor: |
Edward, John T., Lantos, Ivan, Derdall, Gary D., Wong, Sin Cheong |
| Zdroj: |
Canadian Journal of Chemistry; March 1977, Vol. 55 Issue: 5 p812-821, 10p |
| Abstrakt: |
The ionization of 16 thiocarbonyl indicators of overlapping range has been used to establish an acidity function HTfor 10–90% sulfuric acid. Agreement with an earlier HTscale of Tissier and Tissier using different thiocarbonyl indicators is good. Protonation constants pKTH+derived by the classic Hammett–Deyrup approach are in good agreement with those derived by the Bunnett–Olsen relations, but in less satisfactory agreement with those derived by the Marziano–Cimino–Passerini relations. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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