Tetranortriterpenoids and related compounds. Part 25. Two 3,4-secotirucallane derivatives and 2′-hydroxyrohitukin from the bark of Guareacedrata(Meliaceae)

Autor: Akinniyi, John A., Connolly, Joseph D., Rycroft, David S., Sondengam, B. Lucas, Ifeadike, N. Patience
Zdroj: Canadian Journal of Chemistry; September 1980, Vol. 58 Issue: 17 p1865-1868, 4p
Abstrakt: Three new compounds, 3,4-secotirucalla-4(28),7,24-trien-3,21-dioic acid 1, the corresponding 3-monomethyl ester 12, and 2′-hydroxyrohitukin 13, have been isolated from the barkof Guareacedrata(Meliaceae). The structures of 1and 12were confirmed by correlation with methyl 3-oxotirucalla-8,24-dien-21-oate (methyl isoelemonate) 6. The 1H and 13C nmr data are reported.
Databáze: Supplemental Index