| Autor: |
Lawlor, Lawrence J., Martin, Alban, Murchie, Michael P., Passmore, Jack, Sanders, Jeremy C. P. |
| Zdroj: |
Canadian Journal of Chemistry; September 1989, Vol. 67 Issue: 9 p1501-1505, 5p |
| Abstrakt: |
The hydrolysis of TeF5Cl has been followed by 125Te and 19F NMR spectroscopy. The spectra show that the known series (HO)nTeF6−n(n = 2−6) are present. In addition the spectra are consistent with the presence of the previously unreported series (HO)nTeF5−nCl (n = 1–3) as well as unidentified fluorotellurium(IV) species. Evidence is presented for the new species trans- and cis-HOTeF4Cl and cis, mer-(HO)2TeF3Cl. The course of the hydrolysis of TeF5Cl is compared with that of SF5Cl. Keywords: trans-tetrafluorotellurium hydroxychloride, cis-tetrafluorotellurium hydroxychloride, cis,mer-tetrafluorotellurium dihydroxychloride, pentafluorotellurium chloride, hydrolysis. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
