| Autor: |
Brownstein, Sydney, Han, Nam Fong, Gabe, Eric, Lee, Florence |
| Zdroj: |
Canadian Journal of Chemistry; March 1989, Vol. 67 Issue: 3 p551-554, 4p |
| Abstrakt: |
μ4-Oxo-hexa-μ-chloro-tetrakis{(dimethyl sulfoxide)copper(II)}•dimethyl sulfide, from the reaction of copper metal, dimethyl sulfoxide, and carbon tetrachloride crystallizes as orange crystals in the orthorhombic noncentrosymmetric space group P212121with a = 10.5820(20), b = 10.5710(20), and c = 28.255(5) Å and Z = 4. The chirality of the individual molecules is attributed to twists of the planes of the sulfur and carbon atoms of the dimethyl sulfoxide ligands relative to the oxygen–copper–oxygen axes. Keywords: crystal structure, copper cluster complex. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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