Studies Directed to the Total Synthesis of ET 743 and Analogues Thereof:  An Expeditious Route to the ABFGH Subunit

Autor: Zhou, B., Guo, J., Danishefsky, S. J.
Zdroj: Organic Letters; January 2002, Vol. 4 Issue: 1 p43-46, 4p
Abstrakt: In model studies directed to the total synthesis of Et743, a strategic S−C bond formation in systems 26 and 27 was demonstrated. It was further shown that Pictet−Spengler cyclization leading to spiro product 33 exhibits very high stereoselection.
Databáze: Supplemental Index