ZincMediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation ReagentsThis work was supported by SSCI Stipendienfonds der Schweizerischen Chemischen Industrie, ETH Zürich, and DAAD. Dr. H. Rüegger and A. Moreno are acknowledged for their help with NMR spectroscopy.

Autor:	Koller, Raffael, Stanek, Kyrill, Stolz, Daniel, Aardoom, Raphael, Niedermann, Katrin, Togni, Antonio
Zdroj:	Angewandte Chemie. International Edition; June 2009, Vol. 48 Issue: 24 p4332-4336, 5p
Abstrakt:	A fluorry of activity: The transfer of an intact trifluoromethyl group from a hypervalent iodine reagent to an aliphatic alcohol occurs smoothly upon activation by zinc bistriflimide. This constitutes a straightforward method for the preparation of trifluoromethoxy alkyl derivatives, compounds otherwise difficult to access.
Databáze:	Supplemental Index
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