| Autor: |
Sluis, M. van der, Dalmolen, J., Lange, B. de, Kaptein, B., Kellogg, R. M., Broxterman, Q. B. |
| Zdroj: |
Organic Letters; November 2001, Vol. 3 Issue: 24 p3943-3946, 4p |
| Abstrakt: |
The highly diastereoselective addition of allylzinc bromide to imines derived from (R)-phenylglycine amide is reported. Homoallylamines with high enantiomeric purity are obtained from the adducts in three steps on removal of the chiral auxiliary by means of a nonreductive protocol. Removal of the auxiliary by hydrogenation leads to the saturated amines, also in high enantiomeric purity. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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