Acetylacetonatodifluorooxometalates of vanadium and molybdenum: syntheses and crystal structures

Autor: Stasch, Andreas, Schormann, Mark, Prust, Jörg, Roesky, Herbert W., Schmidt, Hans-Georg, Noltemeyer, Mathias
Zdroj: Journal of the Chemical Society, Dalton Transactions; July 7, 2001, Vol. 2001 Issue: 13 p1945-1947, 3p
Abstrakt: [Et4N][HF2] reacted with VO(acac)2 and MoO2(acac)2 in acetonitrile at room temperature with elimination of Hacac to produce the metalates [Et4N][(acac)VOF2] 1 and [Et4N][(acac)MoO2F2 first examples of fluorometalates of vanadium and molybdenum bearing the acetylacetonato group. The crystal structures have been determined.
Databáze: Supplemental Index