A C3-symmetric chiral hexadentate podand ligand based on a tris(pyrazolyl)borate core

Autor: Motson, Graham R., Mamula, Olimpia, Jeffery, John C., McCleverty, Jon A., Ward, Michael D., Zelewsky, Alex von
Zdroj: Journal of the Chemical Society, Dalton Transactions; May 7, 2001, Vol. 2001 Issue: 9 p1389-1391, 3p
Abstrakt: A hexadentate podand ligand having C3 symmetry has been prepared, consisting of a tris(pyrazolyl)borate core bearing pinene-functionalised 2-pyridyl units attached to the C3 position of each pyrazolyl ring such that each arm is a chiral bidentate chelate; complexes with Tl(I) and Tb(III) have been prepared and structurally characterised.
Databáze: Supplemental Index