Amido→azaallyl transformation in sodium amide complexes of (S )-α-(methylbenzyl)benzylamine

Autor: Andrews, Philip C., Duggan, Peter J., Fallon, Gary D., McCarthy, Tom D., Peatt, Anna C.
Zdroj: Journal of the Chemical Society, Dalton Transactions; August 7, 2000, Vol. 2000 Issue: 15 p2505-2507, 3p
Abstrakt: The reaction of (S )-{[(Ph(Me)CH)(PhCH2)]NNa}n with pmdeta (N,N,N ',N ',N "-pentamethyldiethylenetriamine) produces red/green dichroic crystals of the azaallylic complexes {[Ph(Me)CNC(H)Ph]Na·pmdeta}, 3, and {[(PhCH)2N]Na·pmdeta}, 2; by X-ray diffraction 3 is found to be monomeric and structurally similar to the previously characterised 2.
Databáze: Supplemental Index