| Autor: |
Barbarich, Thomas J., Bott, Simon G., Barron, Andrew R. |
| Zdroj: |
Journal of the Chemical Society, Dalton Transactions; June 7, 2000, Vol. 2000 Issue: 11 p1679-1680, 2p |
| Abstrakt: |
The reaction of [(tBu)Ga(μ3-S)]4 with nPrNH2 in toluene solution yields [(tBu)6Ga6(μ3-S)4(μ-S)2(NH2nPr)2] (1), whose thermolysis in the solid state (110 °C), results in the stoichiometric conversion to [(tBu)Ga(μ3-S)]6 (ΔH = 136 kJ mol−1); in contrast, the reaction of [(tBu)Ga(μ3-S)]4 with triflic acid at room temperature yields [(tBu)Ga(μ3-S)]7. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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