Studies of ansa-bis(cyclopentadienyl)tungsten derivatives

Autor: Conway, Stephen L. J., Dijkstra, Tessa, Doerrer, Linda H., Green, Jennifer C., Green, Malcolm L. H., Stephens, Adam H. H.
Zdroj: Journal of the Chemical Society, Dalton Transactions; August 21, 1998, Vol. 1998 Issue: 16 p2689-2696, 8p
Abstrakt: The new compounds [W{(η-C5H4)X(η-C5H4)}Cl2] 1, [W{(η-C5H4)X(η-C5H4)}Me2] 2, [W{(η-C5H4)SiMe2(η-C5H4)}(SPh)2] 3, [W{(η-C5H4)X(η-C5H4)}H(Cl)] 4, [W{(η-C5H4)X(η-C5H4)}H2] 5 and [W{(η-C5H4)X(η-C5H4)}H3]+Y 6, where X = SiMe2, SiEt2 or CMe2CMe2, and Y = BF4 or Cl, have been prepared. The crystal structures of [W{(η-C5H4)X(η-C5H4)}Me2] (X = SiMe2 or CMe2CMe2) have been determined.
Databáze: Supplemental Index