| Autor: |
Sola, Mariela E., Pettigrosso, Rosa S., Bazán, Julio C. |
| Zdroj: |
Journal of Materials Chemistry; February 2001, Vol. 11 Issue: 2 p628-629, 2p |
| Abstrakt: |
Electrode potential measurements for the title cell are presented from which thermodynamic parameters are obtained. The E&z.ccsh; values are lower than those of the same cell with pure electrolyte which results from an increase in the entropy term. There is also a decrease in the αβ transition temperature, which is ascribed to a decrease in the formation energy of the Frenkel defects which in turn is associated with the entropic change. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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