Tandem isomerisationcarbonylation catalysis: highly active palladium(ii) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters
| Autor: | Pugh, Robert I., Pringle, Paul G., Drent, Eite |
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| Zdroj: | Chemical Communications; August 10, 2001, Vol. 2001 Issue: 16 p1476-1477, 2p |
| Abstrakt: | Fast, selective conversion of internal olefins to linear esters is catalysed by Pd(ii) complexes of chelating bis(phospha-adamantyl)diphosphines and the catalysis is acutely sensitive to the ligand backbone and even to the diastereomer used; the results are compared with those for the PBut2 analogue. |
| Databáze: | Supplemental Index |
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