First tether-directed regioselective bis-functionalisation of C70: effects of cation complexation on the redox properties of diastereoisomeric fullerene crown ether conjugates

Autor: Eis, Maurice J. van, Seiler, Paul, Diederich, François, Alvarado, Robert J., Echegoyen, Luis
Zdroj: Chemical Communications; October 7, 2000, Vol. 2000 Issue: 19 p1859-1860, 2p
Abstrakt: The covalently templated bis-functionalisation of C70, employing a dibenzo-18-crown-6 tether, proceeds with complete regiospecificity and provides a bis-addition pattern which is disfavoured in sequential transformations.
Databáze: Supplemental Index