| Autor: |
Reid, Simon J., Freeman, Neil T., Baird, Michael C. |
| Zdroj: |
Chemical Communications; September 21, 2000, Vol. 2000 Issue: 18 p1777-1778, 2p |
| Abstrakt: |
Allylpalladium(ii) compounds react readily in benzene with free phenyl and trityl radicals, generated from the thermal decomposition of phenylazotriphenylmethane, and with free cyclohexyl radicals, generated from the photolysis of (cyclohexyl)(pyridine)cobaloxime; the reactions appear to involve initial attack of the radicals at palladium, followed by secondary processes which convert the coordinated allyl ligands preferentially to terminal rather than internal alkenes. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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