Seven-coordinate Mn2+ ions in [Mn(15-crown-5)(H2O)2]2+ as luminescent probes for dynamic supramolecular events†

Autor: Reid, Howard O. N., Kahwa, Ishenkumba A., White, Andrew J. P., Williams, David J.
Zdroj: Chemical Communications; August 21, 1999, Vol. 1999 Issue: 16 p1565-1566, 2p
Abstrakt: Spectra and temperature dependent decay rates of emission from [Mn(15-crown-5)(H2O)2]2+ ions anchored by a network of O–H&z.dotdot;Br&z.dotdot;H–O bonds in two- and one-dimensional supramolecular arrays of {[Mn(15-crown-5)(H2O)2][TlBr5]}n 1 and {[Mn(15-crown-5)(H2O)2]Br2}n 2 demonstrate the potential efficacy of manganese(II) ions as luminescent probes for supramolecular dynamics.
Databáze: Supplemental Index