Hydrolysis of an iridium–methyl bond, formation of trans-[Ir(CO)(OH)L2] from trans-[Ir(CO)MeL2] [L = PPh2(m-C6H4SO3Na), PPh2(m-C6H4SO3K) or P(C6H4SO3Na)3] upon dissolving in water

Autor: Paterniti, David P., Atwood, Jim D.
Zdroj: Chemical Communications; September 7, 1997, Vol. 1997 Issue: 17 p1665-1666, 2p
Abstrakt: The synthesis, characterization and rapid hydrolysis of trans-[Ir(CO)MeL2] (L = a water-soluble phosphine) to trans-[Ir(CO)(OH)L2] and CH4 are reported.
Databáze: Supplemental Index