Hydrolysis of an iridiummethyl bond, formation of trans-[Ir(CO)(OH)L2] from trans-[Ir(CO)MeL2] [L = PPh2(m-C6H4SO3Na), PPh2(m-C6H4SO3K) or P(C6H4SO3Na)3] upon dissolving in water
Autor: | Paterniti, David P., Atwood, Jim D. |
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Zdroj: | Chemical Communications; September 7, 1997, Vol. 1997 Issue: 17 p1665-1666, 2p |
Abstrakt: | The synthesis, characterization and rapid hydrolysis of trans-[Ir(CO)MeL2] (L = a water-soluble phosphine) to trans-[Ir(CO)(OH)L2] and CH4 are reported. |
Databáze: | Supplemental Index |
Externí odkaz: |