Autor: |
Inose, Yasuo, Moniwa, Shinobu, Aramata, Akiko, Yamagishi, Akihiko, Kyaw-Naing |
Zdroj: |
Chemical Communications; January 7, 1997, Vol. 1997 Issue: 1 p111-112, 2p |
Abstrakt: |
A chiral osmium complex, Δ-(2,2'-bipyridyl) [1,2-bis(4-pyridyl)ethane] chloroosmium Δ-[Os(bpy)2L(Cl)]+, is successfully self-assembled at a monolayer molecular level on a clean Pt electrode in non-aqueous solutions; the self-assembled Δ-[Os(bpy)2LCl]+ ions show a phenomenally repulsive interaction with each other on Pt in chiral-field formation and also in the OsIIOsIII redox reaction, while racemic complexes interact less repulsively with each other. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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