Detection of desterolized sunflower oil in olive oil through isomerized Δ7-sterols

Autor: Biedermann, Maurus, Grob, Konrad, Mariani, Carlo, Schmidt, Joachim P.
Zdroj: Zeitschrift für Lebensmitteluntersuchung und -Forschung A; May 1996, Vol. 202 Issue: 3 p199-204, 6p
Abstrakt: Adulteration of expensive edible oils, such as olive oil, often involves desterolized oils in order to render the adulteration undetectable. Sunflower oil contains characteristic Δ7-sterols, which are readily removed upon strong bleaching. It is shown that these Δ7-sterols do not primarily dehydrate (as do Δ5-sterols), but isomerize to Δ8(14)- and Δ14-sterols. These compounds can be analysed by LC on silica gel or GC on capillary columns with stationary phases of intermediate to high polarity.
Databáze: Supplemental Index