Pyrolysis-gas chromatography with linearly programmed temperature packed and open tubular columns. the thermal degradation of polyolefins

Autor: Kolb, B., Kemmner, G., Kaiser, K. H., Cieplinski, E. W., Ettre, L. S.
Zdroj: Fresenius' Journal of Analytical Chemistry; January 1965, Vol. 209 Issue: 2 p302-312, 11p
Abstrakt: The advantages of the use of programmed temperature open tubular columns for the separation of the pyrolysis products of polymers is again demonstrated, using polyethylene samples. It is also shown that the combination of pyrolysis-gas chromatography with subsequent hydrogenation of the thermal breakdown products using open tubular columns for separation can successfully be used in the identification of the unsaturated components formed during pyrolysis.
Databáze: Supplemental Index