Extraktionsverhalten von Rutheniumnitrosyl-Komplexen in salpetersauren Lösungen

Autor: Blasius, E., Luxenburger, H. J., Neumann, W.
Zdroj: Fresenius' Journal of Analytical Chemistry; January 1984, Vol. 319 Issue: 1 p38-46, 9p
Abstrakt: Solutions of ruthenium-nitrosyl-nitro, ruthenium-nitrosyl-nitro-nitrato and ruthenium-nitrosyl-nitrato complexes can be distinguished clearly from each other by means of paper electrophoresis, extraction chromatography and extractions. The contact time, HNO3-concentration, NO3--concentration, HDBP-content of the organic phase and the addition of F-, SO42-, H2PO4-and C2O42-exert a strong influence on the extraction of the ruthenium-nitrosyl-nitrato complexes with TBP in dodecane.
Databáze: Supplemental Index