| Autor: |
Issa, I. M., Allam, M. G. E. |
| Zdroj: |
Fresenius' Journal of Analytical Chemistry; November 1960, Vol. 175 Issue: 6 p421-428, 8p |
| Abstrakt: |
The reaction between Tl+ solutions and manganate is sluggish. In the titration of Tl+ with manganate solution the end points are always attained earlier than the theoretical. When the reaction is accelerated by NaCl and heating to 45–50° C the end points were found to be concordant with the theoretical values. Titration of manganate with Tl+ solutions gives accurate results in presence of telluric acid but not in its absence. It is also possible to determine Tl+ by oxidation with an excess of K2MnO4 using arsenite as a back titrant for excess oxidant. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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