Transsilylation of disilazanes with 1-chloro-1-methyl-1-silacyclobutane and other triorganylchlorosilanes
| Autor: | Nametkin, N. S., Vdovin, V. M., Babich, E. D. |
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| Zdroj: | Chemistry of Heterocyclic Compounds; January 1967, Vol. 3 Issue: 1 p105-108, 4p |
| Abstrakt: | The first stage of the reaction of hexamethyldisilazane with 1-chloro-1-methyl-1-silacyclotmtane gives 1,3,3,3-tetramethyl-1,1-trimethylenedisilazane, and after that 1,3-dimethyl-1,3-bis(trimethylene)disilazane is formed. The latter reacts with 1-chloro-1-methyl-1-silacyclobutane to give tris[methyl(trimethylene)silyl] amine. From a large number of examples it is shown that transsilylation of disilazanes with chlorosilanes is a general reaction. |
| Databáze: | Supplemental Index |
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