| Autor: |
Zhurkina, I. P., Nedogrei, E. P., Musavirov, R. S., Kondrat'eva, I. A., Rakhmankulov, D. L. |
| Zdroj: |
Chemistry of Heterocyclic Compounds; December 1989, Vol. 25 Issue: 12 p1338-1342, 5p |
| Abstrakt: |
The reaction of hexamethyldisiloxane with 2-ethoxy-1,3-dioxolane is described. It is shown that cleavage of the endo- and exocyclic carbon-oxygen bonds of the ortho ester occurs under mild conditions (16–20‡C) in the presence of acidic catalysts with the formation of 2-(trimethylsiloxy)ethyl formate, the subsequent transformation of which leads to ethyl formate, trimethylethoxysilane, and 1,2-bis(trimethylsiloxy)ethane. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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