| Autor: |
Palant, I. N., Vainshtein, Yu. I., Krasnokut-skaya, D. M., Yakhontov, L. N. |
| Zdroj: |
Chemistry of Heterocyclic Compounds; June 1973, Vol. 9 Issue: 6 p710-712, 3p |
| Abstrakt: |
The polarographic oxidation of a series of 5-azaindoline, 7-azaindoline, and 5,7-diazaindoline derivatives (22 compounds) was studied, and the results are compared with the ease of dehydrogenation of these substances under the influence of quinones. It is shown that E1/2 increases on passing from 7-azaindolines to 5-azaindolines and then to 5,7-diazaindolines. The effect of substituents is satisfactorily described by cross-correlation equations, while the deviations from the correlation are associated with the peculiarities of the lactam-lactim tautomeric equilibrium in a number of 6-hydroxy-5- and 7-azaindolines. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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